Modeling electrical particle thermal energy storage systems for long-duration, grid-electricity storage applications
Not Available
Engineering topics
Publications and source records attributed to Braun, Robert.
Not Available
Long-duration energy storage technologies are being targeted to enable cost-effective, decarbonized energy systems. Particle-based thermal energy storage systems are one promising technology by storing excess electricity or heat as sensible thermal energy in inexpensive, solid, inert particles. These systems are only possible if an effective and economical particle-to-working fluid heat exchanger exists. This study predicts the performance of a proposed, direct-contact, particle-to-air, pressurized fluidized-bed heat exchanger using computational fluid dynamics. The common Eulerian-Eulerian framework for modeling fluidized beds is first benchmarked to experimental results at a previously untested operating condition and application. Then, the benchmarked model evaluates the performance of a proposed design for a commercial-scale version of the novel particle-to-air heat exchanger. The results show pressure drop and gas-phase approach temperatures are advantageous compared to other proposed designs for particle-to-air heat exchangers in the literature; approach temperatures were less than 5 °C and gas-phase pressure drop across the fluidized bed was 32 kPa. The model also highlights the importance of gas distributor design and representation in the Eulerian-Eulerian framework to control fluidization behavior. In conclusion, the model built and benchmarked in this study can be leveraged to advance the design and analysis of these heat exchangers critical to the deployment of a promising long-duration energy storage technology.
Here, in this paper, we present results on performance characterization of solid oxide fuel cell stacks at elevated pressures up to 6 bar a . Stacks are designed and built by Ceres Power, Ltd., and are rated at 1- and 5- kW e . Fuel streams include H 2 / N 2 mixtures, synthetic natural-gas reformate, and simulated anode tail-gas recycle. Elevated operating pressure serves to increase stack electrochemical performance, with the most-pronounced gains found up to 4 bar a . Pressurized operation reduces the extent of methane conversion, promoting more-uniform internal reforming and cooling within the stack. Such cooling is critical at higher-current conditions. A previously developed one dimensional computational stack model is used to provide insight into stack operation. Pressurization is found to slightly increase internal thermal gradients, while promoting more-uniform reactant-concentration profiles across the cell, reducing the likelihood of local fuel starvation. The high fuel dilution brought by anode recycle can modestly decrease stack performance; however, this decrease is recovered through elevated-pressure operation at 3 bar a . Anode recycle further promotes compositional uniformity across the cell. These results reflect that pressurized operation can promote stack performance, while potentially promoting long-term stack durability through uniformity in stack environmental conditions.
This project aims to develop and test novel Reversible Solid Oxide Cells (ReSOCs) specifically designed to yield low area specific resistance, as required to achieve high round trip efficiency in reversible operation at high current density. A key objective is to improve long-term reversible SOC durability; mechanistic degradation models will be used to predict long-term durability using input data from accelerated testing that combines electrochemical life testing with quantitative microstructural and chemical evaluation. The modeling tasks seek to design low-loss, low-cost ReSOC systems using input data from the experimental cell studies. A key challenge is to develop a thermal management strategy that maintains thermally self-sustaining operation while operating the stack at a potential lower than the thermo-neutral steam electrolysis voltage of ~1.3 V, to maintain high efficiency.
Large, centralized power plants are currently the most efficient way to convert fuels such as natural gas to electricity. Fuel cells, however, could become highly efficient generators across a range of sizes from tens of watts to megawatts. In particular, fuel cells with an electrical efficiency of 50% could displace small generators of 25 kilowatts (kW) or less in applications such as remote power, telecommunications, and residential cogeneration. Current 25 kW natural gas generators employing internal combustion engines are typically only 25-30% efficient and expensive to maintain. Furthermore, fuel cells could provide valuable services to the grid, such as the ability to ramp power up or down in response to load conditions. While there are different types of fuel cells, each with their strengths and weaknesses, fuel cells generally are very expensive. For example, lower temperature fuel cells can be started up quickly, but require highly pure hydrogen fuel and expensive catalysts. High-temperature fuel cells can operate on a range of fuels, but they have costly system components and can degrade rapidly.
A linear Fresnel collector design with an operation temperature of 300 degrees C or above typically requires a solar flux concentration ratio of at least 20 on the surfaces of the receiver assembly. For the commercial linear Fresnel collector design in this work, the receiver assembly includes a secondary reflector and an evacuated receiver tube. The high-concentration solar flux may impose additional operating-temperature requirements on the secondary reflector and receiver tube. Thus, a careful heat-transfer analysis is necessary to understand the operating temperature of the receiver assembly component surfaces under design and off-design conditions to guide appropriate material selections. In this work, a numerical heat-transfer analysis is performed to calculate the temperature distribution of the surfaces of the secondary reflector and receiver glass envelope for a commercial collector design. Operating conditions examined in the heat-transfer analysis include various wind speeds and solar concentration ratios. The results indicate a surface temperature higher than 100 degrees C on the secondary reflector surface, which suggests that a more advanced secondary reflector material is needed. The established heat-transfer model can be used for optimization of the other types of linear Fresnel collectors.
This paper presents a technology development initiative focused on delivering SmallSats to orbit a variety of bodies using aerocapture. Aerocapture uses the drag of a single pass through the atmosphere to capture into orbit instead of relying on large quantities of rocket fuel. Using drag modulation flight control, an aerocapture vehicle adjusts its drag area during atmospheric flight through a single-stage jettison of a drag skirt, allowing it to target a particular science orbit in the presence of atmospheric uncertainties. A team from JPL, NASA Ames, and CU Boulder has worked to address the key challenges and determine the feasibility of an aerocapture system for SmallSats less than 180kg. Key challenges include the ability to accurately target an orbit, stability through atmospheric flight and the jettison event, and aerothermal stresses due to high heat rates.
Not Available
Concentrating solar power (CSP) systems employ a sophisticated thermal receiver, power cycle, and a heliostat field, comprised of thousands of mirrors spread over hundreds of acres of land, and are most cost-effective with relatively large quantities of energy storage which can be scheduled for dispatch. We exercise an existing optimization model that maximizes revenue over a year-long time horizon, solved using a standard 48-h look-ahead policy at hourly fidelity on a CSP system under development in California. The system employs molten salt power tower technology with a 150 MWe (net) turbine, eight hours of thermal storage at full load, and a solar field that provides 1.75 times the rated turbine thermal power. The model considers system configuration and interoperability aspects, such as storage tank size, production capacities, and ramp rates, and determines decisions that expedite financing, permitting, and plant design. Relative to results achieved via industry practice, the existing optimization model reduces the number of power cycle (i.e., turbine) start-up events by 86.4%, thereby improving net revenue by more than 8.5% annually; this corresponds to an approximately $140 M increase in net revenue over the lifetime of the plant, taking a step towards advancing the long-term economic viability of large-scale renewable energy systems. Sensitivity analysis on uncertain parameter values provides insight regarding those values that influence profit most significantly.
An innovative design of linear Fresnel secondary receiver assembly is presented here. It includes an evacuated absorber tube and a secondary reflector. The secondary reflector is based on NREL’s new adaptive method. In this paper, a detailed wind load analysis and heat transfer analysis were conducted to assist the ongoing structural design.
An innovative design of linear Fresnel secondary receiver assembly is presented here. It includes an evacuated absorber tube and a secondary reflector. The secondary reflector is based on NREL’s new adaptive method. In this paper, a detailed wind load analysis and heat transfer analysis were conducted to assist the ongoing structural design.
A biomass fast pyrolysis reactor model with detailed reaction kinetics and one-dimensional fluid dynamics was implemented in an equation-oriented modeling environment (Aspen Custom Modeler). Portions of this work were detailed in previous publications; further modifications have been made here to improve stability and reduce execution time of the model to make it compatible for use in large process flowsheets. The detailed reactor model was integrated into a larger process simulation in Aspen Plus and was stable for different feedstocks over a range of reactor temperatures. Sample results are presented that indicate general agreement with experimental results, but with higher gas losses caused by stripping of the bio-oil by the fluidizing gas in the simulated absorber/condenser. Lastly, this integrated modeling approach can be extended to other well-defined, predictive reactor models for fast pyrolysis, catalytic fast pyrolysis, as well as other processes.
No abstract available