The Counterintuitive Relationship between Orbital Energy, Orbital Overlap, and Bond Covalency in CeF 6 2– and CeCl 6 2–
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Engineering topics
Branson, Jacob A.
Publications and source records attributed to Branson, Jacob A..
Analyzing the Intensities of K-Edge Transitions in X 2 Molecules (X = F, Cl, Br) for Use in Ligand K-Edge X-ray Absorption Spectroscopy
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Correction: Thorium amidates function as single-source molecular precursors for thorium dioxide
Correction for ‘Thorium amidates function as single-source molecular precursors for thorium dioxide’ by Mark D. Straub et al. , Chem. Commun. , 2021, 57 , 4954–4957, https://doi.org/10.1039/D1CC00867F.
Straub, Mark D.↗
Correction: Enhanced 5f-δ bonding in [U(C 7 H 7 ) 2 ] - : C K-edge XAS, magnetism, and ab initio calculations
The authors regret that two references to the multi-configurational pair-density functional theory methods used in the wavefunction calculations did not appear in the main article. The references were originally included in the Methods section of the Electronic Supplementary Information as ref. 17a and b, but should also have appeared in the second paragraph on page 9564. The references are listed below as ref. 1 and 2. The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Enhanced 5f-δ bonding in [U(C 7 H 7 ) 2 ] − : C K-edge XAS, magnetism, and ab initio calculations
5f covalency in [U(C 7 H 7 ) 2 ] − was probed with carbon K-edge X-ray absorption spectroscopy (XAS) and electronic structure theory. The results are compared with earlier studies which show that the extent of δ-orbital mixing in [U(C 7 H 7 ) 2 ] 1− is larger than reported previously for U(C 8 H 8 ) 2 .
Qiao, Yusen↗
Thorium amidates function as single-source molecular precursors for thorium dioxide
Here, we report the synthesis of four homoleptic thorium(IV) amidate complexes as single-source molecular precursors for thorium dioxide. Each can be sublimed at atmospheric pressure, with the substituents on the amidate ligands significantly impacting their volatility and thermal stability. These complexes decompose via alkene elimination to give ThO 2 without need for a secondary oxygen source. ThO 2 samples formed from pyrolysis of C-alkyl amidates were found to have higher purity and crystallinity than ThO 2 samples formed from C-aryl amidates.
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗