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Brad Weir

Publications and source records attributed to Brad Weir.

At least 73 records · Page 4

Enhancing Long-Term Trend Simulation of OH Through the Synergy of Model Simulations and Aura Ozone Monitoring Instrument (OMI) NO 2 and HCHO Retrievals

During the last few years, tremendous progress has been made to develop an efficient parameterization module using agile machine learning techniques. The aim of this module is to provide dynamic response of the tropospheric hydroxyl radical (OH) to its major drivers, including trace gases, aerosols, clouds, and meteorology. This module, named ECCOH (pronounced “echo”) and implemented in NASA’s GEOS-5 global model, offers an unrealized opportunity to unravel the convoluted response of OH to its underlying drivers while approaching the accuracy of full-chemistry without incurring excessive computational costs, making it suitable for climate models. However, the accurate representation of OH in ECCOH poses challenges due to the lack of representation of some of its critical inputs such as the abundance of NO 2 and HCHO concentrations. As such, we leverage the well-characterized satellite observations of NO2 and HCHO columns from Aura OMI to enhance their representation in ECCOH using an optimal interpolation method for the time period of 2005 - present. We show how the inclusion of OMI information can affect the spatiotemporal variability and long-term trends of OH, CO, and CH 4 across the globe. Additionally, we underscore the necessity of obtaining high-fidelity information regarding tropospheric ozone from the southern hemisphere from space, a region currently lacking full verification in models, posing a challenge to get a reasonable amount of chemical sink for CH 4 .

OH↗

GEOS Constituent Data Assimilation Beyond Aura MLS: Assimilating NASA SAGE III/ISS Profiles of Stratospheric Water Vapor

Water vapor in the lower stratosphere is an important trace gas for atmospheric chemistry and radiative budget with direct impact on climate. During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the stratospheric ozone loss and the subsequent recovery as well as trends in water vapor linked to surface temperature trends. The SAGE III instrument aboard the International Space Station (ISS) continues the SAGE mission record, with high vertical resolution profiles of water vapor (and other constituents) since mid-2017. The NASA GEOS Earth system model has the capability to assimilate multi-constituents from ground and space-based instruments using the GEOS Constituent Data Assimilation System (CoDAS). Reanalysis products of stratospheric water vapor without data constraints are historically poor, and two recent reanalyses which assimilated stratospheric constituents observed by the Microwave Limb Sounder (MLS) improve the representation of stratospheric composition, including water vapor, when compared against independent observations. The MLS instrument is on NASA's Aura satellite which is expected to be decommissioned in the coming years. Here we demonstrate that while the number of solar occultation observations a day from SAGE III/ISS is about 1 % of the total number of profiles observed globally by MLS, the chemical timescales of water vapor in the lower stratosphere are long enough that the SAGE III/ISS data can provide a useful constraint on the assimilated product. Analyzed water vapor fields from assimilating only SAGE III/ISS water vapor profiles agree well with independent stratospheric observations, including when compared against the frost-point hygrometers at the three NOAA stations. Over the five-year period from 2017 through 2022, the analyzed water vapor using SAGE III/ISS captures many of the features seen with the assimilation of MLS observations. Note, this ability is reduced over regions where the SAGE III/ISS instrument provides infrequent or no observations (associated with the orbit of the ISS), as highlighted in the case study period following the eruption of the tropical underwater volcano Hunga Tonga in early 2022. Nevertheless, there is a clear benefit to the assimilation of stratospheric water vapor from SAGE III/ISS observations, allowing us to continue to monitor stratospheric composition for climate assessments following the impending loss of Aura.

K. Emma Knowland↗

Tropospheric Ozone in the NASA GEOS Model: Effects of Satellite Data Assimilation and Improvements in Background NO x Chemistry

Tropospheric ozone is a major atmospheric oxidant, the primary source of the hydroxyl radical, and a greenhouse gas. In the troposphere, it is produced from the oxidation of carbon monoxide and volatile organic compounds in the presence of nitrogen oxides (NO x =NO+NO 2 ) or has its origins in the stratosphere. The tropospheric ozone burdens in global atmospheric chemistry models disagree by a factor of 1.5, indicating an incomplete understanding of ozone sources and sinks. Here we examine the tropospheric ozone simulation in NASA Global Modeling and Assimilation Office’s (GMAO’s) GEOS model with the GEOS-Chem chemistry mechanism (version 14.2), using observations from satellites, aircraft, ozonesondes, and surface sites. This modeling framework is used to produce GMAO’s GEOS Composition Forecasts (GEOS-CF), and it has been updated extensively with new emission inventories, improved model physics, satellite data assimilation capability, and an up-to-date chemical mechanism that includes tropospheric halogen chemistry and NOx recycling from particulate nitrate. Earlier versions of the model using GEOS-Chem version 12.0 showed an underestimate in tropospheric ozone in the northern hemisphere. We evaluate the ozone simulation in the updated model, focusing on the effects of assimilating satellite NO 2 data from the Ozone Monitoring Instrument (OMI), constraining stratospheric ozone to satellite data, and updates to the NOx chemistry. We will examine changes in the vertical profiles of tropospheric ozone over the US in support of the Tropospheric Emissions: Monitoring of Pollution (TEMPO), and discuss implications for the tropospheric ozone budget.

Viral Shah↗

Broadening Systematic Reanalysis lntercomparisons in the SPARC-Reanalysis lntercomparison Project Phase 2 (S-RIP2): Chemical Reanalyses & Air Quality, Tropospheric Circulation, Extreme Events, and More

Reanalysis datasets are widely used to understand numerous atmospheric processes. Different reanalyses may give very different results for the same diagnostics. The Stratosphere-troposphere Processes And their Role in Climate (SPARC) Reanalysis Intercomparison Project (S-RIP, https://s-rip.github.io/) is a coordinated activity to compare key diagnostics among available reanalyses, identify differences among reanalyses and their underlying causes, provide guidance on appropriate usage of reanalyses in scientific studies, and contribute to future improvements in the reanalysis products via collaborations with reanalysis centers and data users. S-RIP Phase 1 (completed in early 2022) focused primarily on the upper troposphere through the middle atmosphere and processes linking these regions to the troposphere and surface. We look forward to broadening our efforts in Phase 2 (S-RIP2), with new foci including studies of tropospheric circulation, extreme weather events, and their links to the stratosphere, and focusing on evaluation of chemical reanalyses, both those with a stratosphere / upper troposphere focus and those that focus on air quality applications. This presentation will provide a summary of Phase 1 results and discussion of future directions for S-RIP2, emphasizing applications to composition and chemistry studies as well as fostering capacity building for Early Career Scientists.

Sean M Davis↗

Detection of CH 4 Hotspots from NASA’s GEOS Composition Analysis System

Recent research indicates that 8 to 12% of the global oil and gas production methane emissions could be attributed to ultra-emitters, which result in high concentration ‘hotspots’ near point sources. Identifying these emissions in near real time provides useful information to the policy makers and private industry, who are working to reduce their impact. To meet this need, scientists are increasingly analyzing satellite data from the TROPOspheric Monitoring Instrument (TROPOMI) instrument aboard ESA’s Sentinel 5-Precursor mission. While direct analysis of TROPOMI level 2 swath data has been successful in identifying some large emission events, identifying hotpots is challenging because of the imaging noise due to a variety of artifacts and limits in daily coverage. Here we explore possible methodologies to detect methane hotspots using a new, gap-filled, and temporally continuous methane product from NASA’s Goddard Earth Observing System (GEOS) Constituent Data Assimilation System (CoDAS), which assimilates column averaged methane mole fractions from the TROPOMI with capabilities to assimilate other remote sensing measurements. The CoDAS has been expanded from a heritage of stratospheric composition and carbon dioxide assimilation allowing for the support of regional modeling, validation with non-coincident operations, and merging variety of datasets. The current work mainly explores Observing System Simulation Experiments with methane GEOS simulations without assimilation to prepare the groundwork for further experiments with assimilated TROPOMI. First, known hotspots based on the known inventory are identified to demonstrate the capability of the system to point out emission hotspots. In the next step, a variety of machine learning techniques such as Self-Organizing Maps and Deep Learning are explored to automate detection of the plumes. Finally, a few approaches to quantify emissions from the identified hotspots are presented and are evaluated against the inventory. The effort is directed toward a future evaluation of the CoDAS based methane monitoring system’s ability to successfully detect and quantify hotspots.

Nikolay Balashov↗

Broadening Systematic Reanalysis Intercomparisons in the SPARC-Reanalysis Intercomparison Project Phase 2 (S-RIP2): Chemical Reanalyses & Air Quality, Tropospheric Circulation, Extreme Events, and More

Reanalysis datasets are widely used to understand numerous atmospheric processes. Different reanalyses may give very different results for the same diagnostics. The Stratosphere-troposphere Processes And their Role in Climate (SPARC) Reanalysis Intercomparison Project (S-RIP, https://s-rip.github.io/) is a coordinated activity to compare key diagnostics among available reanalyses, identify differences among reanalyses and their underlying causes, provide guidance on appropriate usage of reanalyses in scientific studies, and contribute to future improvements in the reanalysis products via collaborations with reanalysis centers and data users. S-RIP Phase 1 (completed in early 2022) focused primarily on the upper troposphere through the middle atmosphere and processes linking these regions to the troposphere and surface. We look forward to broadening our efforts in Phase 2 (S-RIP2), with new foci including studies of tropospheric circulation, extreme weather events, and their links to the stratosphere, and focusing on evaluation of chemical reanalyses, both those with a stratosphere / upper troposphere focus and those that focus on air quality applications. This presentation will provide a summary of Phase 1 results and discussion of future directions for S-RIP2, emphasizing applications to composition and chemistry studies as well as fostering capacity building for Early Career Scientists.

Sean M Davis↗

GEOS Constituent Data Assimilation Beyond Aura MLS: Assimilating NASA SAGE III/ISS Profiles of Stratospheric Water Vapor

Water vapor in the lower stratosphere is an important trace gas for atmospheric chemistry and radiative budget with direct impact on climate. During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the stratospheric ozone loss and the subsequent recovery as well as trends in water vapor linked to surface temperature trends. The SAGE III instrument aboard the International Space Station (ISS) continues the SAGE mission record, with high vertical resolution profiles of water vapor (and other constituents) since mid-2017. The NASA GEOS Earth system model has the capability to assimilate multi-constituents from ground and space-based instruments using the GEOS Constituent Data Assimilation System (CoDAS). Reanalysis products of stratospheric water vapor without data constraints are historically poor, and two recent reanalyses which assimilated stratospheric constituents observed by the Microwave Limb Sounder (MLS) improve the representation of stratospheric composition, including water vapor, when compared against independent observations. The MLS instrument is on NASA's Aura satellite which is expected to be decommissioned in the coming years. Here we demonstrate that while the number of solar occultation observations a day from SAGE III/ISS is about 1 % of the total number of profiles observed globally by MLS, the chemical timescales of water vapor in the lower stratosphere are long enough that the SAGE III/ISS data can provide a useful constraint on the assimilated product. Analyzed water vapor fields from assimilating only SAGE III/ISS water vapor profiles agree well with independent stratospheric observations, including when compared against the frost-point hygrometers at the three NOAA stations. Over the five-year period from 2017 through 2022, the analyzed water vapor using SAGE III/ISS captures many of the features seen with the assimilation of MLS observations. Note, this ability is reduced over regions where the SAGE III/ISS instrument provides infrequent or no observations (associated with the orbit of the ISS), as highlighted in the case study period following the eruption of the tropical underwater volcano Hunga Tonga in early 2022. Nevertheless, there is a clear benefit to the assimilation of stratospheric water vapor from SAGE III/ISS observations, allowing us to continue to monitor stratospheric composition for climate assessments following the impending loss of Aura.

K. Emma Knowland↗

Global-to-local air quality forecasts using the NASA GEOS Composition Forecast System

Since 2019, the NASA Global Earth Observing System (GEOS) model has been used to generate global, near-real-time estimates and daily five-day forecasts of atmospheric composition at a horizontal resolution of 0.25 degrees (~25 km) from the surface up to the lower mesosphere. This composition forecast system (“GEOS-CF”) combines the GEOS weather forecasting model with the state-of-the-science GEOS-Chem chemistry module to deliver detailed analysis of a wide range of air pollutants, including the policy-relevant species such as ozone, carbon monoxide, nitrogen oxides, sulfur dioxide and fine particulate matter (PM2.5). Because GEOS-CF includes atmospheric levels up through the stratosphere, this system has been leveraged to support the Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite mission and provide stratospheric intrusion alerts to ground-based monitoring stations. We will present recent advances to GEOS-CF which target increased computational efficiency and accuracy. These include the incorporation of simplified chemistry mechanisms to accelerate model forecasts, use of model-observation data fusion techniques to provide highly localized forecasts, and assimilation of satellite observations to produce more accurate model analyses. We further discuss our attempts to make these tools publicly available on platforms outside the NASA domain, such as Google Earth Engine and Amazon Web Services with the goal to facilitate the integration of state-of-the-science air quality information onto platforms used by stakeholders, air quality managers, and the public.

Emma Knowland↗