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Boynton, W. V.

Publications and source records attributed to Boynton, W. V..

At least 37 records · Page 2

Topographically Induced Thermal Effects on Lunar Hydrogen Distributions: Correlated Observations from the LRO LEND and LOLA Instruments

The question of whether water exists on the Moon's surface has long been an enigma to Lunar researchers. Largely, this was due to the thermally extreme lunar surface environment that would seem to preclude any long term maintenance, manufacture, transport or accumulation of hydrogen (H) volatiles over most of the lunar surface. As a result, for many years the cold permanent shadow regions (PSR) in the bottoms of craters near the lunar poles appeared to provide the basic conditions at least for maintenance of lunar hydrogen. Importantly, recent discoveries indicate that there is some hydrogen at the poles. However, the picture of the lunar hydrogen budget may be more complex than the PSR hypothesis has suggested. This evidence comes from observations by the Lunar Exploration Neutron Detector (LEND) onboard the Lunar Reconnaissance Orbiter (LRO) that inclici1te 1) some H concentrations lie outside PSR and 2) though a few of the larger PSR's have high hydrogen, PSR does not appear to be an independent factor influencing the large-scale suppression of polar epithermals observed by LEND and the Lunar Prospector Neutron Spectrometer. In this research we investigate the possibility that the thermal contrast between pole-facing and equator facing-slopes is a factor influencing the surface distributions of lunar H. We perform this bulk correlated observation and study by developing a thermal proxy from slope data of the Lunar Orbiting Laser Altimeter (LOLA) digital elevation model (DEM) which is registered with the collimated LEND epithermal map. From the LOLA transforms we impose a thermal functional decomposition and systematic statistical analysis of the LEND epithermal map. Our hypothesis testing suggests in most high latitude bands studied> +/- 45 deg: Epithermal rates in pole-facing slopes are significantly lower than epithermal rates in equivalent equator-facing slopes. As a control study, we find that there is no statistically significant difference between equivalent east and west facing slopes. This finding suggests topographic modulation of insolation is a factor influencing the lunar H budget. Importantly, this result is consistent with observations in terrestrial, Martian research.

McClanahan, T. P.↗

Isolation Effects on the Moon: High Topographic Slope Observations from the LRO and LOLA Instruments

The extremely low temperatures in the Moon's polar permanent shadow regions (PSR) has long been considered a unique factor necessary for entrapping volatile Hydrogen (H). However, recent discoveries indicate some H concentrations lie outside PSR, suggesting other geophysical factors may also influence H distributions. In this study we consider insolation and its resulting thermal effects as a loss/redistribution process influencing the Moon's near-surface < 1m volatile H budget. To isolate regional (5deg latitude band) insolation effects we correlate two data sets collected from the ongoing, 1.5 year long mapping mission of the Lunar Reconnaissance Orbiter (LRO). Epithermal neutron mapping data from the Lunar Exploration Neutron Detector (LEND) is registered and analyzed in the context of slope derivations from Lunar topography maps produced by the Lunar Observing Laser Altimeter (LOLA). Lunar epithermal neutrons are inferred to be direct geochemical evidence for near-surface H due to the correlated suppression of surface leakage fluxes of epithermal neutrons with increased H concentration. Regional suppressions of neutrons seen in LEND maps are considered localized evidence of H concentration increase in the upper 1 m of the Lunar surface. To quantify spatially localized insolation effects, LEND data are averaged from sparsely distributed pixels, classed as a function of the LOLA slope derivations.

McClanahan, T. P.↗

(Ca,Mg)-Carbonate and Mg-Carbonate at the Phoenix Landing Site: Evaluation of the Phoenix Lander's Thermal Evolved Gas Analyzer (TEGA) Data Using Laboratory Simulations

Calcium carbonate (4.5 wt. %) was detected in the soil at the Phoenix Landing site by the Phoenix Lander s The Thermal and Evolved Gas Analyzer [1]. TEGA operated at 12 mbar pressure, yet the detection of calcium carbonate is based on interpretations derived from thermal analysis literature of carbonates measured under ambient (1000 mbar) and vacuum (10(exp -3) mbar) conditions [2,3] as well as at 100 and 30 mbar [4,5] and one analysis at 12 mbar by the TEGA engineering qualification model (TEGA-EQM). Thermodynamics (Te = H/ S) dictate that pressure affects entropy ( S) which causes the temperature (Te) of mineral decomposition at one pressure to differ from Te obtained at another pressure. Thermal decomposition analyses of Fe-, Mg-, and Ca-bearing carbonates at 12 mbar is required to enhance the understanding of the TEGA results at TEGA operating pressures. The objectives of this work are to (1) evaluate the thermal and evolved gas behavior of a suite of Fe-, Mg-, Ca-carbonate minerals at 1000 and 12 mbar and (2) discuss possible emplacement mechanisms for the Phoenix carbonate.

Sutter, B.↗

Insolation Effects on Lunar Hydrogen: Observation from the LRO LEND and LOLA Instruments

The Moon's polar permanent shadow regions (PSR) have long been considered the unique repository for volatile Hydrogen (H) Largely, this was due to the extreme and persistently cold environment that has been maintained over eons of lunar history. However, recent discoveries indicate that the H picture may be more complex than thc PSR hypothesis suggests. Observations by the Lunar Exploration Neutron Detect (LEND) onboard the Lunar Reconnaissance Orbiter (LRO) indicate some H concentrations lie outside PSR. Similarly, observations from Chandraayan-l's M3 and Deep Impact's EPOXI near infra-red observations indicate diurnal cycling of volatile H in lower latitudes. These results suggest other geophysical phenomena may also play a role in the Lunar Hydrogen budget. In this presentation we review the techniques and results from the recent high latitude analysis and apply similar techniques to equatorial regions. Results from our low latitude analysis will be reported. We discuss interpretations and implications for Lunar Hydrogen studies

McClanahan, T. P.↗

Lunar Reconnaissance Orbiter (LRO) Observations with the Lunar Exploration Neutron Detector (LEND): Neutron Suppression Regions (NSR) and Polar Hydrogen

Orbital detection of neutrons has become the dominant remote sensing technique for detecting and inferring H concentrations and its spatial distribution beneath planetary surfaces [Lawrence et al, (2010) Icarus, 205, pp. 195-209, Mitrofanov et al (2007) Science 297(5578), 78-81]. Indications for the presence of localized and relatively high water content was provided by LRO and LCROSS. LEND identified Cabeus, as the most promising LCROSS impact site [Mitrofanov I. et al. (2010) Science, 330, 483], and instruments onboard LRO and LCROSS have measured signatures of water, H2 and other volatiles in the impact plume [Colaprete A. et al. (2010) Science, 339,463, Gladstone R. et al. (2010) Science, 330, 472].

Chin, G.↗

Correlation of Lunar South Polar Epithermal Neutron Maps: Lunar Exploration Neutron Detector and Lunar Prospector Neutron Detector

The Lunar Reconnaissance Orbiter's (LRO), Lunar Exploration Neutron Detector (LEND) was developed to refine the lunar surface hydrogen (H) measurements generated by the Lunar Prospector Neutron Spectrometer. LPNS measurements indicated a approx.4,6% decrease in polar epithermal fluxes equivalent to (1.5+/-0,8)% H concentration and are direct geochemical evidence indicating water /high H at the poles. Given the similar operational and instrumental objectives of the LEND and LPNS systems, an important science analysis step for LEND is to test correlation with existing research including LPNS measurements. In this analysis, we compare corrected low altitude epithermal rate data from LPNS available via NASA's Planetary Data System (PDS) with calibrated LEND epithermal maps using a cross-correlation technique

McClanahan, Timothy P.↗

Carbon and Oxygen Stable Isotope Measurements of Martian Atmospheric CO2 by the Phoenix Lander

Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars [1]. The isotopic composition of the martian atmosphere has been measured using a number of different methods (Table 1), however a precise value (<1%) has yet to be achieved. Given the elevated Delta(sup 13)C values measured in carbonates in martian meteorites [2-4] it has been proposed that the martian atmosphere was enriched in 13C [8]. This was supported by measurements of trapped CO2 gas in EETA 79001[2] which showed elevated Delta(sup 13)C values (Table 1). More recently, Earth-based spectroscopic measurements of the martian atmosphere have measured the martian CO2 to be depleted in C-13 relative to CO2 in the terrestrial atmosphere[ 7, 9-11]. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Mars Phoenix Lander [12] included a magnetic-sector mass spectrometer (EGA) [13] which had the goal of measuring the isotopic composition of martian atmospheric CO2 to within 0.5%. The mass spectrometer is a miniature instrument intended to measure both the martian atmosphere as well as gases evolved from heating martian soils.

Niles, Paul B.↗

Epithermal Neutron Observations and Lunar South Pole Targeting for LCROSS Impact Planning using the Lunar Reconnaissance Orbiter (LRO), Lunar Exploring Neutron Detector (LEND)

LCROSS impact targeting and planning efforts included quantifying South Polar epithermal neutron flux depressions in early LEND mapped results to maximize the expected plume Hydrogen (H) yield. Epithermal neutron surface fluxes are a key geochemical indicator of surface Hydrogen (H) concentration inferred to be elevated in polar permanent shadow regions (PSR). LCROSS impact target regions were delineated as (PSR) using illumination modeling of polar topography. To quantify targets potential yield for LCROSS, LEND epithermal neutron flux observations were integrated over LCROSS targets of interest and compared to background observations. Discussion will define methods review impact prior estimates and contrast post impact results.

McClanahan, T. P.↗

Evidence for Calcium Carbonate at the Phoenix Landing Site

The Phoenix mission has recently finished its study of the north polar environment of Mars with the aim to help understand both the current climate and to put constraints on past climate. An important part of understanding the past climate is the study of secondary minerals, those formed by reaction with volatile compounds such as H2O and CO2. This work describes observations made by the Thermal and Evolved-Gas Analyzer (TEGA) on the Phoenix Lander related to carbonate minerals. Carbonates are generally considered to be products of aqueous processes. A wet and warmer climate during the early history of Mars coupled with a much denser CO2 atmosphere are ideal conditions for the aqueous alteration of basaltic materials and the subsequent formation of carbonates. Carbonates (Mg- and Ca-rich) are predicted to be thermodynamically stable minerals in the present martian environment, however, there have been only a few indications of carbonates on the surface by a host of orbiting and landed missions to Mars. Carbonates (Mg-rich) have been suggested to be a component (2-5 wt %) of the martian global dust based upon orbital thermal emission spectroscopy. The identifications, based on the presence of a 1480 cm-1 absorption feature, are consistent with Mgcarbonates. A similar feature is observed in brighter, undisturbed soils by Mini-TES on the Gusev plains. Recently, Mg-rich carbonates have been identified in the Nili Fossae region by the CRISM instrument onboard the Mars Reconnaissance Orbiter. Carbonates have also been confirmed as aqueous alteration phases in martian meteorites so it is puzzling why there have not been more discoveries of carbonates by landers, rovers, and orbiters. Carbonates may hold important clues about the history of liquid water and aqueous processes on the surface of Mars.

Boynton, W. V.↗

Summary of Results from the Mars Phoenix Lander's Thermal Evolved Gas Analyzer

The Mars Phoenix Scout Mission with its diverse instrument suite successfully examined several soils on the Northern plains of Mars. The Thermal and Evolved Gas Analyzer (TEGA) was employed to detect evolved volatiles and organic and inorganic materials by coupling a differential scanning calorimeter (DSC) with a magnetic-sector mass spectrometer (MS) that can detect masses in the 2 to 140 dalton range [1]. Five Martian soils were individually heated to 1000 C in the DSC ovens where evolved gases from mineral decompostion products were examined with the MS. TEGA s DSC has the capability to detect endothermic and exothermic reactions during heating that are characteristic of minerals present in the Martian soil.

Sutter, B.↗

The Mars Phoenix Thermal Evolved-Gas Analysis: The Role of an Organic Free Blank in the Search for Organics

The Thermal Evolved-Gas Analyzer (TEGA) instrument onboard the 2007 Phoenix Lander will perform differential scanning calorimetry (DSC) and evolved-gas analysis of soil samples collected from the surface. Data from the instrument will be compared with Mars analog mineral standards, collected under TEGA Mars-like conditions to identify the volatile-bearing mineral phases [1] (e.g., Fe-oxyhydroxides, phyllosilicates, carbonates, and sulfates) found in the Martian soil. Concurrently, the instrument will be looking for indications of organics that might also be present in the soil. Organic molecules are necessary building blocks for life, although their presence in the ice or soil does not indicate life itself. The spacecraft will certainly bring organic contaminants to Mars even though numerous steps were taken to minimize contamination during the spacecraft assembly and testing. It will be essential to distinguish possible Mars organics from terrestrial contamination when TEGA instrument begins analyzing icy soils. To address the above, an Organic Free Blank (OFB) was designed, built, tested, and mounted on the Phoenix spacecraft providing a baseline for distinguishing Mars organics from terrestrial organic contamination. Our objective in this report is to describe some of the considerations used in selecting the OFB material and then report on the processing and analysis of the final candidate material

Lauer, H. V., Jr.↗

Phoenix Lander's Thermal Evolved Gas Analyzer: Differential Scanning Calorimeter and Mass Spectrometer Database Development

The Mars Scout Phoenix lander will land in the north polar region of Mars in May, 2008. One objective of the Phoenix lander is to search for evidence of past life in the form of molecular organics that may be preserved in the subsurface soil. The Thermal Evolved Gas Analyzer (TEGA) was developed to detect these organics by coupling a simultaneous differential thermal analyzer (SDTA) with a mass spectrometer. Martian soil will be heated to approx.1000 C and potential organic decomposition products such as CO2, CH4 etc. will be examined for with the MS. TEGA s SDTA will also assess the presence of endothermic and exothermic reactions that are characteristic of soil organics and minerals as the soil is heated. The MS in addition to detecting organic decompositon products, will also assess the levels of soil inorganic volatiles such as H2O, SO2, and CO2. Organic detection has a high priority for this mission; however, TEGA has the ability to provide valuable insight into the mineralogical composition of the soil. The overall goal of this work is to develop a TEGA database of minerals that will serve as a reference for the interpretation of Phoenix-TEGA. Previous databases for the ill-fated Mars Polar Lander (MPL)-TEGA instrument only went to 725 C. Furthermore, the MPL-TEGA could only detect CO2 and H2O while the Phoenix-TEGA MS can examine up to 144 atomic mass units. The higher temperature Phoenix-TEGA SDTA coupled with the more capable MS indicates that a higher temperature database is required for TEGA interpretation. The overall goal of this work is to develop a differential scanning calorimeter (DSC) database of minerals along with corresponding MS data of evolved gases that can used to interpret TEGA data during and after mission operations. While SDTA and DSC measurement techniques are slightly different (SDTA does not use a reference pan), the results are fundamentally similar and thus DSC is a useful technique in providing comparative data for the TEGA database. The objectives of this work is to conduct DSC and MS analysis up to 1000 C of select minerals that may be found in the martian soil.

Sutter, B.↗

Mars 2007 Phoenix Scout Mission Organic Free Blank: Method to Distinguish Mars Organics from Terrestrial Organics

The Mars 2007 Phoenix Scout Mission successfully launched on August 4, 2007, for a 10-month journey to Mars. The Phoenix spacecraft is scheduled to land on May 25, 2008. The primary mission objective is to study the history of water and evaluate the potential for past and present habitability in Martian arctic ice-rich soil [1]. Phoenix will land near 68 N latitude on polygonal terrain presumably created by ice layers that are expected to be a few centimeters under loose soil materials [2,3]. The Phoenix Mission will assess the potential for habitability by searching for organic molecules in ice or icy soils at the landing site. Organic molecules are necessary building blocks for life, although their presence in the ice or soil does not indicate life itself. Phoenix will search for organic molecules by heating soil/ice samples in the Thermal and Evolved-Gas Analyzer (TEGA, [4]). TEGA consists of 8 differential scanning calorimeter (DSC) ovens integrated with a magnetic-sector mass spectrometer with a mass range of 2-140 daltons [4]. Endothermic and exothermic reactions are recorded by the TEGA DSC as samples are heated from ambient to approx.1000 C. Evolved gases, including organic molecules and fragments if present, are simultaneously measured by the mass spectrometer during heating.

Ming, D. W.↗

Thermal and Evolved Gas Analysis of Geologic Samples Containing Organic Materials: Implications for the 2007 Mars Phoenix Scout Mission

The Thermal and Evolved Gas Analyzer (TEGA) instrument scheduled to fly onboard the 2007 Mars Phoenix Scout Mission will perform differential scanning calorimetry (DSC) and evolved gas analysis (EGA) of soil samples and ice collected from the surface and subsurface at a northern landing site on Mars. We have been developing a sample characterization data library using a laboratory DSC integrated with a quadrupole mass spectrometer to support the interpretations of TEGA data returned during the mission. The laboratory TEGA test-bed instrument has been modified to operate under conditions similar to TEGA, i.e., reduced pressure (e.g., 100 torr) and reduced carrier gas flow rates. We have previously developed a TEGA data library for a variety of volatile-bearing mineral phases, including Fe-oxyhydroxides, phyllosilicates, carbonates, and sulfates. Here we examine the thermal and evolved gas properties of samples that contain organics. One of the primary objectives of the Phoenix Scout Mission is to search for habitable zones by assessing organic or biologically interesting materials in icy soil. Nitrogen is currently the carrier gas that will be used for TEGA. In this study, we examine two possible modes of detecting organics in geologic samples; i.e., pyrolysis using N2 as the carrier gas and combustion using O2 as the carrier gas.

Lauer, H. V., Jr.↗

Two Successive Martian Years on the Orbit: Similarities and Differences of CO2 Seasonal Cycle from HEND/ODYSSEY Data

The three years of Mars Odyssey successful work on the martian orbit provide a lot of new information about peculiarities of long term variations of CO2 seasonal cycle. To start such analysis we have used observations of neutron albedo of Mars obtained by High Energy Neutron detector (HEND) mounted onboard Mars Odyssey spacecraft. The high latitude northern and southern regions of Mars are affected by global redistribution of atmospheric CO2 which resulted in 25% of atmospheric mass condensed on martian surface of these regions during winter period of time. The seasonal deposit is formed starting from 60N/60S latitudes and achieve its maximal thickness about 1 m at latitudes close to martian poles. Changes of CO2 deposit thickness is the reason for significant variations of neutron flux above martian poles from summer to winter seasons because CO2 frost effectively hides upper water rich surface layers from the orbit observations in neutrons and gamma-rays. This effect was used to estimate column density of CO2 deposit at different latitudes on North and South of Mars and reconstruct multidimensional model of CO2 deposit showing how snow depth varies as function of latitude, longitude and time. In this presentation we tried to make a next step in our study of martian seasonal CO2 cycle and look for similarities and differences between two successive martian years.

Litvak, M. L.↗

Distribution and Abundance of Mars' Atmospheric Argon

One and one half Mars years (MY 26 and 27) of atmospheric Argon measurements are described and studied in the context of understanding how Argon, a minor constituent of Mars atmosphere that does not condense at Mars temperatures, can be used to study martian circulation and dynamics. Argon data are from the 2001 Mars Odyssey Gamma Subsystem (GS) of the suite of three instruments comprising the Gamma Ray Spectrometer (GRS). A comprehensive data analysis including gamma-ray production and attenuation by the atmosphere is included. Of particular interest is the enhanced abundance of Ar over the observed Ar abundance at lower latitudes at south (up to a factor of 10) and north (up to a factor of 4) polar regions during winter. Calibration of the measurements to actual Ar abundance is possible because GS measurements cover the same latitude and season as measurements made by the gas chromatograph mass spectrometer (GCMS) on Viking Landers 1 and 2 (VL1 and VL2). [2].

Sprague, A. L.↗

South Polar Ar Enhancement as a Tracer for Southern Winter Horizontal Meridional Mixing

Measurements made by the Gamma Ray Spectrometer (GRS) on Mars Odyssey during 2002 and 2003 show an obvious increase in the gamma flux of 1294 keV gamma rays resulting from the decay of (41)Ar. (41)Ar is made by the capture of thermal neutrons by atmospheric (40)Ar. The increase measured above the southern polar region has permitted calculation of the increase in mixing ratio of Ar from L(sub s) 8 to 100 between latitudes 75 S and 90 S. The peak in Ar enhancement occurs about 200 Earth days after CO2 freeze-out has begun, indicating that up to this time equatorward meridional mixing is rapid enough to move enhanced Ar from the polar regions northward. Although the CO2 frost depth continues to increase from L(sub s) 110 deg to 190 deg, the Ar enhancement steadily decreases to its baseline value reached at about L(sub s) 200 deg. Our data permit an estimate of the horizontal eddy mixing coefficient useful for constraining equatorward meridional mixing during southern winter and a characteristic mixing time for the polar southern winter atmosphere. Also, using the drop in excess Ar measured by the GRS from L(sub s) 110 deg to 200 deg, we estimate an eddy coefficient appropriate for meridional mixing of the entire Ar excess back to the baseline value. The horizontal eddy mixing coefficients are derived using Ar as a tracer much as the vertical eddy mixing coefficient for the Earth's troposphere is derived using CH4 as a minor constituent tracer. The estimation of meridional mixing for high latitudes at Mars is important for constraining parameters used in atmospheric modeling and predicting seasonal and daily behavior. The calculations are order of magnitude estimates that should improve as the data set becomes more robust and improves our models.

Sprague, A. L.↗

Arabia and Memnonia Equatorial Regions with High Content of Water: Data from HEND/Odyssey

After one martian year of neutron mapping measurements by the High Energy Neutron Detector (HEND) onboard the Mars Odyssey spacecraft, a map of the planet was produced showing the summer season in each hemisphere when winter deposition of CO2 on the surface is absent. The data for northern and southern poleward water-rich regions are presented. Here we discuss the HEND results for two equatorial regions, Arabia and Memnonia, which were found to be associated with a rather strong depression of epithermal and high energy neutrons.

Mitrofaov, I. G.↗