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Boumsellek, S.

Publications and source records attributed to Boumsellek, S..

8 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Pulsed, gridded electron reversal ionizer

The design and performance of a new-type source of negative ions is presented. This device retains the idea of the so-called reversal electron attachment detector to produce low-energy electrons by reversing electron trajectories at an electrode. Electrons are produced in the present device by several ribbon filaments that surround a cylindrical wire grid. They are accelerated through the grid, then decelerated to zero or near-zero velocity at the surface of a tube. The tube (anode) is perforated with small holes through which effuse the target molecules. Electrons attach to form either parent and/or fragment negative ions. Attachment takes place at a location above the anode corresponding to a match between the electron energy and the attachment resonance energy. Negative ions are pulsed out of the attachment region and focused onto the entrance plane of a quadrupole mass selector. Electron and ion trajectory calculations are presented and the performance illustrated with six molecules having attachment resonances in the range 0.0-2.2 eV. The detection sensitivity is below 1 part-per-trillion, with a calculated conversion rate of 1.3 percent. Signal nonlinearity is discussed in terms of ion space-charge effects. The device also produces positive ions, and an analogous treatment may be carried through to characterize its performance in this mode.

Boumsellek, S.↗
NASA NTRS1992

Increased response of the reversal electron attachment detector and modeling of ion space-charge effects

Design and sensitivity tests of a modified version of the so-called reversal electron attachment detector (READ) are presented. The new version uses a spherical cathode capable of emitting higher electron currents. As in the original READ (which used a planar emitter) electrons are focused into an electrostatic mirror which reverses their trajectories. In the reversal region electrons have essentially zero energy and attach to target molecules to form negative ions. The electron gun lens system has been modified using a field and trajectory code with space charge included. Electron trajectories have been calculated for 1-mA current focused into a reversal region of 3.5-mm diameter. The detection limit of the apparatus is approximately 25 times lower than for the original READ. Nonlinearity in the measured signal vs electron current is described by a model in which a spherical ball of ions expands outward with velocity determined by the space-charge force and the initial velocity of ion formation.

Boumsellek, S.↗
NASA NTRS1992

Negative-ion formation in the explosives RDX, PETN, and TNT using the Reversal Electron Attachment Detection (READ) technique

In the search for high sensitivity and direct atmospheric sampling of trace species, techniques have been developed such as atmospheric-sampling, glow-discharge ionization (ASGDI), corona discharge, atmospheric pressure ionization (API), electron-capture detection (ECD), and negative-ion chemical ionization (NICI) that are capable of detecting parts-per-billion to parts-per-trillion concentrations of trace species. These techniques are based on positive- or negative-ion formation via charge-transfer to the target, or electron capture under multiple-collision conditions in a Maxwellian distribution of electron energies at the source temperature. One drawback of the high-pressure, corona- or glow-discharge devices is that they are susceptible to interferences either through indistinguishable product masses, or through undesired ion-molecule reactions. The ASGDI technique is relatively immune from such interferences, since at target concentrations of less than 1 ppm the majority of negative ions arises via electron capture rather than through ion-molecule chemistry. A drawback of the conventional ECD, and possibly of the ASGDI, is that they exhibit vanishingly small densities of electrons with energies in the range 0-10 millielectron volts (meV), as can be seen from a typical Maxwellian electron energy distribution function at T = 300 K. Slowing the electrons to these subthermal (less than 10 meV) energies is crucial, since the cross section for attachment of several large classes of molecules is known to increase to values larger than 10(exp -12) sq cm at near-zero electron energies. In the limit of zero energy these cross sections are predicted to diverge as epsilon(exp -1/2), where epsilon is the electron energy. In order to provide a better 'match' between the electron energy distribution function and attachment cross section, a new concept of attachment in an electrostatic mirror was developed. In this scheme, electrons are brought to a momentary halt by reversing their direction with electrostatic fields. At this turning point the electrons have zero or near-zero energy. A beam of target molecules is introduced, and the resultant negative ions extracted. This basic idea has been recently improved to allow for better reversal geometry, higher electron currents, lower backgrounds, and increased negative-ion extraction efficiency. We present herein application of the so-called reversal electron attachment detector (READ) to the study of negative-ion formation in the explosives molecules RDX, PETN, and TNT under single-collision conditions.

Chutijian, Ara↗
NASA NTRS1992

Negative-ion formation in the explosives RDX, PETN, and TNT by using the reversal electron attachment detection technique

First results of a beam-beam, single-collision study of negative-ion mass spectra produced by attachment of zero-energy electrons to the molecules of the explosives RDX, PETN, and TNT are presented. The technique used is reversal electron attachment detection (READ) wherein the zero-energy electrons are produced by focusing an intense electron beam into a shaped electrostatic field which reverses the trajectory of electrons. The target beam is introduced at the reversal point, and attachment occurs because the electrons have essentially zero longitudinal and radial velocity. The READ technique is used to obtain the 'signature' of molecular ion formation and/or fragmentation for each explosive. Present data are compared with results from atmospheric-pressure ionization and negative-ion chemical ionization methods.

Boumsellek, S.↗
NASA NTRS1990

Ionization processes in collisions of open-shell atoms. III - The autoionizing states of nitrogen

Results of a study of the energy spectra of electrons produced in collisions of N atoms with inert gases at low keV energies are reported. Ionization here is partly due to production of the (1Dnl) autoionizing states of nitrogen and partly due to another mechanism, which is presumably quasi molecular Auger ionization. A discussion of the assignments of the autoionizing states is presented.

Boumsellek, S.↗