X-ray diffraction from shock driven Sn microjets
Here, in situ x-ray diffraction was performed on shock-generated microjets composed of Sn and Sn–4Ag. Under low pressure drives (~21 GPa), a significant fraction of the jet volume was found to be in the β-Sn phase, and these crystallites were much smaller than the initial grain size of the material. Significant quantities of amorphous (molten) material were observed for higher drive pressures (~25–35 GPa). The extent of melting at these pressures was greater than would be predicted for uniaxial shock loading. Diffraction patterns from the Sn–4Ag alloy showed a peak that is consistent with the expected Ag 3 Sn intermetallic phase. This peak remained evident under drive conditions where the sample was otherwise fully amorphous. This indicates a slushy or a mixed phase of liquid Sn and solid Ag 3 Sn. Given the eutectic character of this alloy, this observation is attributed to a kinetic limitation on the dissolution of Ag 3 Sn. This implies that a much broader range of drive conditions will lead to mixed phase jets and ejecta than would be predicted from the equilibrium melt boundary of such alloys.