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Bhartia, P. K.

Publications and source records attributed to Bhartia, P. K..

At least 163 records · Page 9

The Effect of Solar Proton Events on Ozone and Other Constituents

Solar proton events (SPEs) can cause changes in constituents in the Earth's middle atmosphere. The highly energetic protons cause ionizations, excitations, dissociations, and dissociative ionizations of the background constituents. Complicated ion chemistry leads to HO(x) production and dissociation of N2 leads to NO(y) production. Both the HO(x) and NO(y) increases can result in changes to ozone in the stratosphere and mesosphere. The HO(x) increases lead to short-lived ozone decreases in the mesosphere and upper stratosphere due to the short lifetimes of the HO(x) constituents. The NO(y) increases lead to long-lived stratospheric ozone changes because of the long lifetime of NO(y) constituents in this region. The NO(y) induced ozone changes are generally decreases, however, the NO(y) constituents can interfere with chlorine and bromine radicals in the lowest part of the stratosphere and cause ozone increases. Temperature changes have been predicted to occur as a result of the larger SPEs. Eleven SPEs have caused measurable atmospheric variations since 1969. Neutral wind variations were measured shortly after the July 1982 and April 1984 SPEs. The recent July 2000 SPE caused NO(x) increases that lasted for two months past the event. The two periods of largest SPEs (August 1972 and October 1989) caused ozone decreases that lasted for several weeks past the events.

Jackman, Charles H.↗

NASA's Experience with UV Remote Using SBUV and TOMS Instruments

This paper will discuss key features of the NASA algorithm that has been used to produce several highly popular geophysical products from the Solar Backscatter Ultraviolet (SBUV) and Total Ozone Mapping Spectrometer (TOMS) series of instruments. Since these instruments have a limited number of wavelengths, many innovative algorithmic approaches have been developed over the years to derive maximum information from these sensors. We will use Global Ozone Monitoring Experiment (GOME) data to test the assumptions made in these algorithms and show what additional information is contained in the GOME hyperspectral data. At NASA we are using this information to improve the SBUV and TOMS algorithms, as well as to develop more efficient algorithms to process GOME data.

Bhartia, P. K.↗

Current Status of Aerosol Retrievals from TOMS

Properties of atmospheric aerosols over all land and water surfaces are retrieved from TOMS measurements of backscattered radiances. The TOMS technique, uses observations at two wavelengths. In the near ultraviolet (330-380 nm) range, where the effects of gaseous absorption are negligible. The retrieved properties are optical depth and a measure of aerosol absorptivity, generally expressed as single scattering albedo. The main sources of error of the TOMS aerosol products are sub-pixel cloud contamination and uncertainty on the height above the surface of UV-absorbing aerosol layers. The first error source is related to the large footprint (50 x 50 km at nadir) of the sensor, and the lack of detection capability of sub-pixel size clouds. The uncertainty associated with the height of the absorbing aerosol layers, on the other hand, is related to the pressure dependence of the molecular scattering process, which is the basis of the near-UV method of absorbing aerosol detection. The detection of non-absorbing aerosols is not sensitive to aerosol layer height. We will report on the ongoing work to overcome both of these difficulties. Coincident measurements of high spatial resolution thermal infrared radiances are used to address the cloud contamination issue. Mostly clear scenes for aerosol retrieval are selected by examining the spatial homogeneity of the IR radiance measurements within a TOMS pixel. The approach to reduce the uncertainty associated with the height of the aerosol layer by making use of a chemical transport model will also be discussed.

Torres, O.↗

The Retrieval of Ozone Profiles from Limb Scatter Measurements: Theory

An algorithm is presented for retrieving vertical profiles of O3 concentration using measurements of UV and visible light scattered from the limb of the atmosphere. The UV measurements provide information about the O3 profile in the upper and middle stratosphere, while only visible wavelengths are capable of probing the lower stratospheric O3 profile. Sensitivity to the underlying scene reflectance is greatly reduced by normalizing measurements at a tangent height high in the atmosphere (approximately 55 km), and relating measurements taken at lower altitudes to this normalization point. To decrease the effect of scattering by thin aerosols/clouds that may be present in the field of view, these normalized measurements are then combined by pairing wavelengths with strong and weak O3 absorption. We conclude that limb scatter can be used to measure O3 between 15 km and 50 km with 2-3 km vertical resolution and better than 10% accuracy.

Flittner, D. E.↗

Earth Probe Total Ozone Mapping Spectrometer (TOMS) Data Product User's Guide

Two data products from the Earth Probe Total Ozone Mapping Spectrometer (EP/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The EP/ TOMS began taking measurements on July 15, 1996. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio is used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement are monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the first year of data. The Level-2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level-3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. Level-3 files containing estimates of LTVB at the Earth surface and tropospheric aerosol information are also available, Detailed descriptions of both HDF data-files and the CD-ROM product are provided.

McPeters, R.↗

Impact of Tropospheric Aerosol Absorption on Ozone Retrieval from buv Measurements

The impact of tropospheric aerosols on the retrieval of column ozone amounts using spaceborne measurements of backscattered ultraviolet radiation is examined. Using radiative transfer calculations, we show that uv-absorbing desert dust may introduce errors as large as 10% in ozone column amount, depending on the aerosol layer height and optical depth. Smaller errors are produced by carbonaceous aerosols that result from biomass burning. Though the error is produced by complex interactions between ozone absorption (both stratospheric and tropospheric), aerosol scattering, and aerosol absorption, a surprisingly simple correction procedure reduces the error to about 1%, for a variety of aerosols and for a wide range of aerosol loading. Comparison of the corrected TOMS data with operational data indicates that though the zonal mean total ozone derived from TOMS are not significantly affected by these errors, localized affects in the tropics can be large enough to seriously affect the studies of tropospheric ozone that are currently undergoing using the TOMS data.

Torres, O.↗

ADEOS Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

Two data products from the Total Ozone Mapping Spectrometer (ADEOS/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The ADEOS/ TOMS began taking measurements on September 11, 1996, and ended on June 29, 1997. The instrument measured backscattered Earth radiance and incoming solar irradiance; their ratio was used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement were monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the 9-month data record. The Level 2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level 3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. The Level 3 files containing estimates of UVB at the Earth surface and tropospheric aerosol information will also be available. Detailed descriptions of both HDF data files and the CDROM product are provided.

Krueger, A.↗

Satellite Estimation of Spectral Surface UV Irradiance: Effect of Horizontally Homogeneous Clouds - 2

The local variability of UV irradiance at the Earth's surface is mostly caused by clouds in addition to the seasonal variability. Parametric representations of radiative transfer RT calculations are presented for the convenient solution of the transmission T of ultraviolet radiation through plane parallel clouds over a surface with reflectivity R(sub s). The calculations are intended for use with the Total Ozone Mapping Spectrometer (TOMS) measured radiances to obtain the calculated Lambert equivalent scene reflectivity R for scenes with and without clouds. The purpose is to extend the theoretical analysis of the estimation of UV irradiance from satellite data for a cloudy atmosphere. Results are presented for a range of cloud optical depths and solar zenith angles for the cases of clouds over a low reflectivity surface R(sub s) less than 0.1, over a snow or ice surface R(sub s) greater than 0.3, and for transmission through a non-conservative scattering cloud with single scattering albedo omega(sub 0) = 0.999. The key finding for conservative scattering is that the cloud-transmission function C(sub T), the ratio of cloudy-to clear-sky transmission, is roughly C(sub T) = 1 - R(sub c) with an error of less than 20% for nearly overhead sun and snow-free surfaces. For TOMS estimates of UV irradiance in the presence of both snow and clouds, independent information about snow albedo is needed for conservative cloud scattering. For non-conservative scattering with R(sub s) greater than 0.5 (snow) the satellite measured scene reflectance cannot be used to estimate surface irradiance. The cloud transmission function has been applied to the calculation of UV irradiance at the Earth's surface and compared with ground-based measurements.

Krothov, N.↗

Satellite Estimates of Single Scattering Albedo and Optical Depth of Biomass Burning Carbonaceous Aerosols

Satellite based estimates of aerosol single scattering albedo (ssa), over both land and water surfaces, have been obtained for the first time using measurements of backscattered radiation in the near ultraviolet by the Total Ozone Mapping Spectrometer (TOMS). The retrieval of ssa and aerosol optical depth is based on the strong spectral contrast in the near-UV resulting from the interaction between the particle absorption and scattering (both Rayleigh and Mie) processes. We use the multi-year data set on backscattered radiances by the TOMS family of instruments to analyze the time and space variability of biomass burning generated carbonaceous aerosols. Results of a comparative analysis of satellite derived optical depth and available sunphotometer measurements will also be presented.

Torres, O.↗

Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

Two data products from the Total Ozone Mapping Spectrometer (TOMS) onboard Nimbus-7 have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio is used in ozone retrievals. Changes in the instrument sensitivity are monitored by a spectral discrimination technique using measurements of the intrinsically stable wavelength dependence of derived surface reflectivity. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and drift is less than 1.0 percent per decade. The Level-2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level-3 product contains daily total ozone amount and reflectivity in a I - degree latitude by 1.25 degrees longitude grid. The Level-3 product also is available on CD-ROM. Detailed descriptions of both HDF data files and the CD-ROM product are provided.

McPeters, Richard D.↗

Spectral analyses, climatology, and interannual variability of Nimbus-7 TOMS version 6 total column ozone

This reference publication presents selected results from space-time spectral analyses of 13 years of version 6 daily global ozone fields from the Total Ozone Mapping Spectrometer (TOMS). One purpose is to illustrate more quantitatively the well-known richness of structure and variation in total ozone. A second purpose is to provide, for use by modelers and for comparison with other analysts' work, quantitative measures of zonal waves 1, 2, 3, and medium-scale waves 4-7 in total ozone. Their variations throughout the year and at a variety of latitudes are presented, from equatorial to polar regions. The 13-year averages are given, along with selected individual years which illustrate year-to-year variability. The largest long wave amplitudes occur in the polar winters and early springs of each hemisphere, and are related to strong wave amplification during major warning events. In low attitudes total ozone wave amplitudes are an order of magnitude smaller than at high latitudes. However, TOMS fields contain a number of equatorial dynamical features, including Rossby-gravity and Kelvin waves.

Stanford, J. L.↗

Meteor 3/total ozone mapping spectrometer observations of the 1993 ozone hole

The development of the springtime (September-November) Antarctic ozone hole was observed by the Meteor 3/total ozone mapping spectromter (TOMS) to result in the lowest ozone value, 85 DU (Dobson units) on October 8, 1993, ever measured by TOMS. During late September and early October the region of extremely low ozone values was centered on the geographical pole between 85 deg S and 90 deg S. The geographical extent of the ozone hole region, the area within the 220-DU contour, reached a maximum during the first week in October at a near-circular area covering 24 x 10(exp 6) sq km reaching to the southern tip of South America. This approximately matched the 1992 area record. After the maximum area was reached in early October, the 1993 ozone hole region was significantly larger than during 1992 throughout the remainder of the month of October. The very low ozone values over the Antarctic continent have been confirmed by independent ground-based data. Unlike 1992, the formation of the 1993 Antarctic ozone hole does not coincide with unusually low ozone values observed over most of the globe for the past 2 years. The most recent ozone data from Meteor 3/TOMS show that there has been a recovery at all latitudes from the extraordinarily low values observed during 1992 and part of 1993 after the June 1991 eruption of Mount Pinatubo. Meteor 3/TOMS is described and compared with Nimbus 7/TOMS during the 1991 to May 1993 overlap period. Observations of the 1992 ozone hole are presented from both instruments and are shown to agree within 5 DU.

Herman, J. R.↗

Application of the Langley plot method to the calibration of the solar backscattered ultraviolet instrument on the Nimbus 7 satellite

The concept of the well-known Langley plot technique, used for the calibration of ground-based instruments, has been generalized for application to satellite instruments. In polar regions, near summer solstice, the solar backscattered ultraviolet (SBUV) instrument on the Nimbus 7 satellite samples the same ozone field at widely different solar zenith angles. These measurements are compared to assess the long-term drift in the instrument calibration. Although the technique provides only a relative wavelength-to-wavelength calibration, it can be combined with existing techniques to determine the drift of the instrument at any wavelength. Using this technique, we have generated a 12-year data set of ozone vertical profiles from SBUV with an estimated accuracy of +/- 5% at 1 mbar and +/- 2% at 10 mbar (95% confidence) over 12 years. Since the method is insensitive to true changes in the atmospheric ozone profile, it can also be used to compare the calibrations of similar SBUV instruments launched without temporal overlap.

Bhartia, P. K.↗

Effect of stratospheric aerosol on ozone profile from BUV measurements

Results of a simulation study on the effects of optically thick stratospheric sulfate aerosol layers on the backscattered ultraviolet radiation (buv) in the range 256-340 nm are presented. In general, the increased Mie scattering produced by the aerosols results in an enhancement of the buv radiation. The increase is approximately linear with optical depth and strongly depends on solar zenith angle and aerosol layer altitude in relation to the ozone maximum. The effect is greatest at those wavelenghts whose contribution functions peak in the vicinity of the densest part of the aerosol layer. The aerosol induced perturbation of the buv field affects the ozone profile retrieval from space measurements by the Solar Backscatter Ultraviolet Experiment (SBUV) experiment. In the tropical stratosphere, the retrieved ozone between 25 and 45 km is underestimated as a result of increased Mie scattering. On the other hand, an algorithm related effect causes the retrieved ozone below 25 km to be overestimated by an amount similar to the stratospheric deficit.

Torres, Omar↗

Calibration of the NOAA 11 solar backscatter ultraviolet (SBUV/2) ozone data set from 1989 to 1993 using in-flight calibration data and SSBUV

Total ozone and ozone profiles are currently being measured by solar backscatter ultraviolet (SBUV/2) instruments onboard NOAA polar orbiting spacecraft using the backscattered ultraviolet technique. The NOAA 11 SBUV/2 operational data set, reprocessed from January 1989 to May 1993 (version 6), includes an updated algorithm and revised prelaunch and postlaunch calibrations of the geometrical albedo observations used to derive ozone values. The postlaunch calibration revisions remove time dependent errors in the ozone amounts due to instrument drift, while the revised prelaunch calibration corrects the absolute value of retrieved ozone. The prelaunch corrections are a result of calibration checks from in-orbit comparisons of ultraviolet geometric albedos measured by shuttle SBUV (SSBUV) and the NOAA 11 SBUV/2. Geometric albedo comparison data are further corrected using a radiative transfer code to account for the small difference in observing conditions between the two spacecraft. The postlaunch corrections rely on in-flight calibration and solar irradiance data to account for time dependent changes in instrument gain, thermal response, and instrument diffuser degradation over time. Comparison of data from three SSBUV flights, which occurred about one year apart, with concurrent SBUV/2 data provided an independent check of the time dependent change derived from the in-flight calibration data. Time independent corrections result in an increase of about 1% for total ozone, 5% for ozone at 1 mbar, and near 0% at 15 mbar. The time dependent corrections amount to an increase of 2% for total ozone, 10% for ozone near 1 mbar, and 3% at 15 mbar at the end of the current record in May 1993. Recent laboratory studies indicate that the absolute radiance calibrations may still be in error by a few percent which results in ozone profile values that are too low. The SBUV/2 total and ozone profile data are compared to the Nimbus SBUV data during the period when the data overlapped. Total ozone values agree to about 1%, while ozone profile differences range from -4% to +6%, depending on latitude and altitude, relative to SBUV. These differences are not statistically significant given the uncertainties of the two data sets.

Hilsenrath, E.↗

Comparison of satellite measurements of ozone and ozone trends

Measurements of ozone retrieved from satellite instruments over the 1979-1991 period are compared. The instruments used are the total ozone mapping spectrometer (TOMS), the solar backscattered ultraviolet experiment (SBUV), and stratospheric aerosol and gas experiments (SAGE) I and II. Although there is good agreement between the absolute densities of ozone as measured by the various instruments, the long-term changes (1979-1990) disagree sharply as a function of pressure and in the integrated ozone amount. In the upper stratosphere, SBUV trends are negative with maximum values of about -1.5%/year at high latitudes. Combined SAGE I and II trends are slightly positive in this region and peak near 0.5%/year at equatorial latitudes. In the lower stratosphere, SBUV trends reflect small decreases in ozone, generally less than -0.4%/year except at high southern latitudes where the trends rearch values of approximately -1.5%/year. SAGE ozone trends exhibit large decreases particularly in the equatorial regions where decreases of 3-6%/year are seen at pressures between 60 and 90 mbar. At higher latitudes, SAGE trends are more comparable to SBUV trends in the lower stratosphere. Total ozone trends from TOMS and SBUV agree within their uncertainties. Near-zero trends are indicated at low latitudes, and larger, negative trends (approximately -0.5%/year) are indicated near the poles. The SAGE column ozone trends depend upon the base level altitude of integration but do not exhibit a strong latitude dependence.

Rusch, D. W.↗

Northern middle-latitude ozone profile features and trends observed by SBUV and Umkehr, 1979-1990

A comparison of Umkehr ozone profile data with the reprocessed solar backscatter ultraviolet (SBUV) ozone data in the northern middle-latitude region, 30 deg to 50 deg N, is reported. Although significant biases exist between the two types of observations, the long-term variations and least squares linear regression trends agree remarkably well over the comparison period of 1979 to 1990. The ozone trend in the upper stratosphere is of the order of -0.9%/yr. Near 25 km, little if any trend appears, but a larger negative trend is seen in the lower stratosphere near 15 km. Comparisons show that the average annual ozone cycles in the profiles also agree well. The upper stratospheric ozone results are consistent with photochemical model predictions of ozone depletion near 40 km that are due to the release of anthropogenically produced chlorofluorocarbons. The lower stratospheric ozone trend results are in reasonable agreement with published ozonesonde data trends. It is shown that the ozone trends in the lower stratospheric layers impact significantly on the total ozone trend of the order of -0.47%/yr. The good agreement now seen between the two types of observations suggest that the combined ground-based and satellite approach could provide a valuable database for long-term monitoring of stratospheric ozone for trends and extraordinary variations.

Deluisi, J. J.↗