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Amdur, I.

Publications and source records attributed to Amdur, I..

13 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Scattering of high-velocity He atoms by C/CH3/4 and Si/CH3/4

Fast helium beams are employed to probe short-range potentials in tetramethylmethane and tetramethylsilane, and throw light on the relations between these more complex reactions and such reactions as He-CH4 and He-SiH4. Earlier work on scattering of helium and argon beams by polyatomic molecules (fluorinated methanes, sulfur hexafluoride, silane, germane) are at variance with these results, as neither of the above systems can be represented as a cluster of four CH4 molecules, Effective He-H potentials based on scattering data are identical for the two systems studied but are much larger than the corresponding CH4 potential. A model in which centers of force are located along the bonds rather than at the nuclei is suggested for further testing.

Amdur, I.↗
NASA NTRS1976

Scattering of high-velocity He and Ar beams by methane, silane, and germane

Fast He and Ar beams have been scattered by room-temperature CH4, SiH4, and GeH4 to obtain average atom-molecule potentials for He-CH4, He-SiH4, He-GeH4, Ar-CH4, and Ar-GeH4. Somewhat unexpectedly, the potential for He-GeH4 was intermediate between He-CH4 and He-SiH4; this apparent discrepancy, however, correlates with the bond polarities. The potential for Ar-CH4 can be satisfactorily predicted from that for He-CH4 by means of simple potential models and combination rules. The analogous prediction for Ar-GeH4 is unsatisfactory; reasons for the discrepancy are discussed.

Amdur, I.↗
NASA NTRS1976

Scattering of high-velocity Ar atoms by CO2, OCS, and CS2

Fast Ar beams have been scattered by room-temperature CO2, OCS, and CS2 to obtain average atom-molecule potentials. The results are consistent with other scattering measurements on similar systems, and are also in excellent agreement with available theoretical calculations based on an electron-gas model. Decomposition of the atom-molecule potentials into constituent atom-atom potentials shows that such a representation can be utilized with fair accuracy but that a definite discrepancy exists.

Amdur, I.↗
NASA NTRS1972

Molecular beams in chemistry.

The molecular-beam technique is a means for producing isolated atoms or molecules within a narrow range of speed and solid angle. The phenomena studied with molecular beams can be classified as single-particle interactions, many-particle interactions, and two particle-interactions. The results of scattering experiments fall into two categories including collisions that do not result in atomic rearrangements and collisions that do. Experimental methods are discussed, giving attention to low-energy beams, high-energy beams, and intermediate-energy beams. Examples are presented to illustrate the information that can be obtained from elastic, inelastic, and reactive scattering.

Jordan, J. E.↗