A photoionization study of ion pair formation from CFCl3
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Ajello, J. M.↗
Engineering topics
Ajello, J. M.
Publications and source records attributed to Ajello, J. M..
High resolution threshold photoelectron spectroscopy by electron attachment
A system is provided for determining the stable energy levels of a species ion, of an atomic, molecular, or radical type, by application of ionizing energy of a predetermined level, such as through photoionization. The system adds a trapping gas to the gaseous species to provide a technique for detection of the energy levels. The electrons emitted from ionized species are captured by the trapping gas, only if the electrons have substantially zero kinetic energy. If the electrons have nearly zero energy, they are absorbed by the trapping gas to produce negative ions of the trapping gas that can be detected by a mass spectrometer. The applied energies (i.e. light frequencies) at which large quantities of trapping gas ions are detected, are the stable energy levels of the positive ion of the species. SF6 and CFCl3 have the narrowest acceptance bands, so that when they are used as the trapping gas, they bind electrons only when the electrons have very close to zero kinetic energy.
Chutjian, A.↗
Extreme ultraviolet observations from Voyager 1 encounter with Jupiter
Observations of the optical extreme ultraviolet spectrum of the Jupiter planetary system during the Voyager 1 encounter have revealed previously undetected physical processes of significant proportions. Bright emission lines of S(+2), S(+3), O(+2) indicating an electron temperature of 100,000 K have been identified in preliminary analyses of the Io plasma torus spectrum. Strong auroral atomic and molecular hydrogen emissions have been observed in the polar regions of Jupiter near magnetic field lines that map the torus into the atmosphere of Jupiter. The observed resonance scattering of solar hydrogen Lyman alpha by the atmosphere of Jupiter and the solar occultation experiment suggest a hot thermosphere (greater than or equal to 1000 K) with a large atomic hydrogen abundance. A stellar occultation by Ganymede indicates that its atmosphere is at most an exosphere.
Broadfoot, A. L.↗
Four UV observations of the interstellar wind by Mariner 10 - Analysis with spherically symmetric solar radiation models
Four Mariner 10 observations of interplanetary hydrogen 1216-A and helium 584-A emissions are analyzed by using radiation models that employ spherically symmetric solar radiation fields. It is shown that the measured 584-A intensities can be represented with a statistical accuracy of about 10% by a model that assumes spherical symmetry for the 584-A solar radiation and that the 1216-A intensities can be represented to within 15% by a model based on spherically symmetric solar corpuscular and EUV radiation. An interstellar wind velocity of 22 km/s, a helium number density of 0.008 per cu cm, and an interstellar neutral-gas temperature of 1500 K near the solar system are obtained from Copernicus satellite measurements.
Ajello, J. M.↗
Solar wind latitudinal variations deduced from Mariner 10 interplanetary H /1216 A/ observations
The Mariner 10 H (1216-A) interplanetary observations are examined by using models that consider anisotropies in the solar fluxes. It is verified that the dominant contribution to asymmetric structure in the Mariner 10 H (1216-A) data is a latitudinal variation of the solar-wind flux and of the solar wind velocity, leading to a hydrogen atom lifetime that is latitude dependent. The average lifetime at 1 AU is found to increase from the solar equator to the solar poles by about 25%. This allows interstellar hydrogen to penetrate closer to the solar poles than to the equator. A general analytic model is constructed for evaluating the neutral hydrogen density distribution in interplanetary space. This model takes into account the latitude-dependent ionization rate. When this model is applied to the Mariner 10 H (1216-A) data, it is shown to be capable of matching the observations with a statistical accuracy of 5%. The effect of this latitudinal variation on H (1216-A) sky background maps is to produce a latitudinal shift in the maximum toward the north ecliptic pole.
Witt, N.↗
Simultaneous H/1216 A/ and He/584 A/ observations of the interstellar wind by Mariner 10
In late 1973 and early 1974 the Mariner 10 spacecraft performed four roll calibration maneuvers (RCM). The Ultraviolet Spectrometer (UVS) measured the intensity of both He(584 A) and H(1216 A) emissions from interplanetary gas. The data and the observational geometry have been described by Broadfoot and Kumar (1978). Analysis of these 4 sets of observations is extremely important since they are the first simultaneous intensity measurements of H and He emissions free of geocoronal contamination to be recorded in one day, thus precluding significant variations in the solar fluxes.
Ajello, J. M.↗
Photocatalytic oxidation of organic compounds on Mars
Ultraviolet-stimulated catalytic oxidation is proposed as a mechanism for the destruction of organic compounds on Mars. The process involves the presence of gaseous oxygen, UV radiation, and a catalyst (titanium dioxide), and all three of these have been found to be present in the Martian environment. Therefore it seems plausible that UV-stimulated oxidation of organics is responsible for degrading organic molecules into inorganic end products.
Chun, S. F. S.↗
An interpretation of Mariner 10 helium /584 A/ and hydrogen /1216 A/ interplanetary emission observations
Measurements of the interplanetary emissions of both He(584 A) and H(1216 A) on January 28, 1974, a time of solar minimum, are reported and discussed. An analysis of the Mariner 10 ultraviolet spectrometer data shows that a simultaneous measurement of both emissions results in a self-consistent determination of the physical properties of the interstellar wind. With the aid of a model the number densities of helium and hydrogen outside the solar system were found to be 0.008 + or - 0.003/cu cm and 0.04 (+0.03, -0.02)/cu cm, respectively, which indicates a He/H ratio of 0.20 (+0.30, -0.13). Values characterizing the helium cone, interstellar wind temperature, effective lifetime of hydrogen atoms in the solar system, and downstream direction of the interstellar wind are presented.
Ajello, J. M.↗
The composition of Phobos - Evidence for carbonaceous chondrite surface from spectral analysis
In connection with a need for more definitive information concerning the composition of Phobos in a study of its origin, an ultraviolet-visible-infrared reflectance spectrum of the Martian satellite was compiled from the Mariner 9 ultraviolet spectrometer, Viking lander imaging, and ground-based photometric data. The probable surface composition of Phobos was deduced by comparing the obtained spectrum with the spectra of asteroids of known composition. The considered data show that the reflectivity of Phobos is flat from 1100 to 400 nm but decreases sharply in the ultraviolet to about 1 percent at 212 nm. The reflectance spectrum is similar to the spectra of asteroids Ceres and Pallas which were found to have surface compositions similar to that of carbonaceous chondrites. It is concluded that the surface composition of Phobos is also similar to that of carbonaceous chondrites. The results of the investigation point to different modes of origin for Mars and Phobos.
Pang, K. D.↗
Multicolor observations of Phobos with the Viking lander cameras - Evidence for a carbonaceous chondritic composition
The reflectivity of Phobos has been determined in the spectral region from 0.4 to 1.1 micrometers from images taken with a Viking lander camera. The reflectivity curve is flat in this spectral interval and the geometric albedo equals 0.05 + or - 0.01. These results, together with Phobos's reflectivity spectrum in the ultraviolet, are compared with laboratory spectra of carbonaceous chondrites and basalts. The spectra of carbonaceous chondrites are consistent with the observations, whereas the basalt spectra are not. These findings raise the possibility that Phobos may be a captured object rather than a natural satellite of Mars.
Pollack, J. B.↗
Ultraviolet spectrometer experiment for the Voyager mission
An objective grating spectrometer covering the wavelength range of 500 to 1700 A with a 10-A resolution is employed for the Voyager ultraviolet spectrometer experiment. In determining the composition and structure of the atmospheres of Saturn, Jupiter and several satellites, the ultraviolet spectrometer will rely on airglow mode observations to measure radiation from the atmospheres due to resonant scattering of solar flux, and the occultation mode for assessments of the atmospheric extinction of solar or stellar radiation as the spacecraft enters shadow zones. Since it is capable of prolonged stellar observations in the 500 to 1000 A wavelength range, the spectrometer is expected to make important contributions to exploratory studies of UV sources.
Broadfoot, A. L.↗
Studies of Ar and N2 using threshold photoelectron spectroscopy by electron attachment /TPSA/
Threshold photoelectron spectra of Ar and N2 are studied by a technique called threshold photoelectron spectroscopy by electron attachment, which involves the attachment of the threshold electron to SF6 followed by the detection of SF6(-). Studies on Ar provide a measure of the rejection ratio for nonthreshold electrons of this technique. A rotational propensity rule is given which states that an autoionizing N2 state prefers to decay to N2(+) states with a minimum change in rotational angular momentum.
Chutjian, A.↗
Photoelectron spectroscopy by electron attachment
Technique detects threshold photoelectrons for atoms and molecules with high resolution, yet requires no electron optics setup.
Ajello, J. M.↗
A photoionization study of the formation of NO2/+/ by reaction of excited O2/+/ ions with NO
Photoionization mass spectrometer results are presented for the first observation of the ion-molecule reaction in which O2(+) + NO yields NO2(+) + O. The reaction is energetically possible for ground state O2(+) ions in the lowest vibrational level. Photoionization efficiency curves for NO(+), O2(+), and NO2(+) are presented and compared, with special emphasis on autoionization features. In addition to the production of NO2(+) by the cited reaction, there is also a possibility for NO2(+) formation by the process O2 + NO(+) yielding NO2(+) + O. This reaction is calculated to be exothermic for incident photon energies of 11.73 eV.
Ajello, J. M.↗
Complex refractive index of Martian dust - Wavelength dependence and composition
The size distribution and complex refractive index of Martian dust-cloud particles observed in 1971 with the Mariner 9 UV spectrometer are determined by matching the observed single-scattering albedo and phase function with Mie-scattering calculations for size distributions of spheres. Values of phase function times single-scattering albedo are presented for 12 wavelength intervals in the range from 190 to 350 nm, and best-fit values are obtained for the absorption index. It is found that the absorption index of the dust particles increases with decreasing wavelength from 350 to about 210 nm and then drops off shortward of 210 nm, with a structural shoulder occurring in the absorption spectrum between 240 and 250 nm. A search for a candidate material that can explain the strong UV absorption yields TiO2, whose anatase polymorph has an absorption spectrum matching that of the Martian dust. The TiO2 content of the dust particles is estimated to be a few percent or less.
Pang, K.↗
High-resolution threshold photoelectron spectroscopy by electron attachment
A new technique for measuring high-resolution threshold photoelectron spectra of atoms, molecules, and radicals is described. It involves photoionization of a gaseous species, attachment of the threshold, or nearly zero electron to some trapping molecule (here SF6 or CFCl3), and mass detection of the attachment product (SF6/-/ or Cl/-/ respectively). This technique of threshold photoelectron spectroscopy by electron attachment was used to measure the spectra of argon and xenon at 11 meV (FWHM) resolution, and was also applied to CFCl3.
Ajello, J. M.↗
A photoionization study of the charge transfer reactions - Xe/+/ + O2 yields O2/+/ + Xe and O2/+/ + Xe yields Xe/+/ + O2
The charge transfer reactions: Xe(+) + O2 yields O2(+) + Xe and O2(+) + Xe yields Xe(+) + O2 were studied using photoionization mass spectroscopy. It is shown that the reaction of Xe(+)(2P-3/2) ions with O2 molecules is much more efficient than the reaction of Xe(+)(2P-1/2) ions with O2 molecules. The charge transfer reaction of O2(+) ions with Xe atoms was detected for O2(+) ions in the a 4Pi-u state.
Ajello, J. M.↗
A photoionization mass spectrometer study of CFCl3, CF2Cl2, and CF3Cl
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Ajello, J. M.↗