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Adler, I.

Publications and source records attributed to Adler, I..

At least 19 records

Interatomic Auger transitions in maximal valent V and Cr compounds

The sensitivity of the intensities of the L(3)M(23)M(45) and L(3)M(45)M(45) Auger transitions toward the 3d character in the valence band has been demonstrated by using argon ion bombardment as a means of in situ reduction for the valence state of V and Cr in their maximal valent compounds. The selected V(5+) and Cr(6+) compounds were V2O5, NH4VO3, K2Cr2O7, K2CrO4, and CrO3. Auger and X-ray photoelectron spectra of fresh samples were obtained, and the samples were then subjected to ion bombardment of various durations. The subsequent spectra were recorded to monitor possible alterations due to the reduction of the cation valence state. The interatomic to intraatomic transitions of the Auger spectra transitions of the Auger spectra were observed dynamically and in situ. In particular, the intensity of the cation L(3)M(23)N(45) transitions was observed to increase dramatically with ion bombardment. The correlation between the interatomic Auger transition and covalency as well as the movements of the 3d electrons are discussed.

Yin, L. I.

Are early magnesium-rich basalts widespread on the moon

Orbital X-ray data indicate that high-magnesium material systematically occurs along mare/terra boundaries in all the lunar nearside basins for which there is orbital X-ray coverage. These peripheral units appear to represent the earliest stages of volcanism within each of the basins, although they were not necessarily emplaced at the same time in lunar history. High-magnesium subsurface layers excavated by post-mare impact craters in central Mare Crisium and Mare Fecunditatis suggest that the peripheral units are the only visible edges of a basin-wide basalt layer, largely buried by younger less-magnesian flows. This evidence suggests that early magnesium-rich mare basalts are widespread on the moon and that their volumes may be greatly underestimated. Abundant early mare deposits of this type would place severe constraints on models of mare basalt petrogenesis.

Andre, C. G.

Application of Remote Sensing to the Chesapeake Bay Region. Volume 1: Executive summary

The proceedings are presented of a conference, jointly sponsored by the National Aeronautics and Space Administration, the U.S. Environmental Protection Agency, and the University of Maryland. The purpose of the Conference was to assemble representatives of federal and state government agencies engaged in research on the condition and evolution of the Chesapeake Bay to compose a status report, to present current activities and future plans, and to recommend a long-range future course of policies and programs.

Chen, W. T.

Evidence for a high-magnesium subsurface basalt in Mare Crisium from orbital X-ray fluorescence data

Orbital X-ray fluorescence data taken by the Apollo 15 mission over Mare Crisium are analyzed in order to detect surface occurrences of the magnesium-rich materials found in the Luna 24 core sample. Apollo 15 data of the surface soils of the Luna 24 landing site, expressed as Al/Si and Mg/Si ratios, are found to be well correlated with the composition of the less than 74 micron fraction of the core sample. Orbital data indicate that most surface areas of the southern part of Mare Crisium have magnesium contents lower than or equal to that of the landing site, with the exception of areas in the vicinities of the post-mare craters Picard and Pierce and an area northeast of the Luna 24 site. The crater material is interpreted to be a magnesium-rich subsurface basalt excavated by crater formation, which may represent the material from which magnesium-rich Luna 24 samples, including olivine gabbro and olivine vitrophyre, were derived.

Andre, C. G.

A new color correlation method applied to XRF Al/Si ratios and other lunar remote sensing data

Orbital X-ray fluorescence Al/Si intensity ratios, corrected for variations in solar activity, are correlated with normal albedo, elevation measurements from laser altimetry data, and gamma ray data in the 2.75-8.60 MeV range. Each of these data sets is placed into a digital array consisting of 1/4 deg latitude by 1/4 deg longitude pixels. Information relative to the correlation of Al/Si ratios with each of the other data sets is presented in the following forms: (1) histograms are given for each data set to show the frequency distribution within the areas of common coverage; (2) density plots are produced from the plot of a two-dimensional array consisting of the Al/Si ratio vs the other parameter value for each pixel; and (3) color correlation maps are produced by placing the two-dimensional array into a 3 x 3 matrix consisting of nine equal subarrays containing an equal number of data points.

Clark, P. E.

Utilization of independent solar flux measurements to eliminate nongeochemical variation in X-ray fluorescence data

It is shown that the direct method of solar activity correction for lunar XRF data produces XRF data with better statistics than uncorrected data. Direct measurements of the solar flux made by Solrad 10 are converted to emissions of the sun from two assumed temperature regions. These emissions are ratioed to produce emission measure ratios, sensitive indicators of shifts in solar activity. The Tucker-Koren model (1971) of the solar flux is used in the calculation of EMRs and in the calculation of theoretical lunar Si, Al, and Mg fluorescence of maria and highland soils. Al/Si(Mg/Si) ratios calculated at a 'normal' EMR of 0.030 are divided by Al/Si(Mg/Si) ratios at particular EMRs. The relationship between EMR and the quotients of this division, called 'correction factors', is well explained by empirically derived power law functions.

Clark, P. E.

Lunar surface chemistry - A new imaging technique

Detailed chemical maps of the lunar surface have been constructed by applying a new weighted-filter imaging technique to Apollo 15 and Apollo 16 X-ray fluorescence data. The data quality improvement is amply demonstrated by (1) modes in the frequency distribution, representing highland and mare soil suites, which are not evident before data filtering, and (2) numerous examples of chemical variations which are correlated with small-scale (about 15 kilometer) lunar topographic features.

Andre, C. G.

Lunar elemental analysis obtained from the Apollo gamma-ray and X-ray remote sensing experiment

Gamma-ray and X-ray spectrometers carried in the service modules of the Apollo 15 and Apollo 16 spacecraft were employed for compositional mapping of the lunar surface. The measurements involved the observation of the intensity and characteristic energy distribution of gamma rays and X-rays emitted from the lunar surface. A large-scale compositional map of over 10 percent of the lunar surface was obtained from an analysis of the observed spectra. The objective of the X-ray experiment was to measure the K spectral lines from Mg, Al, and Si. Spectra were obtained and the data were reduced to Al/Si and Mg/Si intensity ratios and ultimately to chemical ratios. Analyses of the results have indicated (1) that the Al/Si ratios are highest in the lunar highlands and considerably lower in the maria, and (2) that the Mg/Si concentrations generally show the opposite relationship. The objective of the gamma-ray experiment was to measure the natural and cosmic-ray-induced activity emission spectrum. At this time, the elemental abundances for Th, U, K, Fe, Ti, Si, and O have been determined over a number of major lunar regions. Regions of relatively high natural radioactivity were found in the Mare Imbrium and Oceanus Procellarum regions.

Trombka, J. I.

Orbital chemistry - Lunar surface analysis from the X-ray and gamma ray remote sensing experiments

The X-ray and gamma-ray lunar surface remote sensing experiments conducted by the Apollo 15 and 16 are discussed. The data indicate mare basins that are extensively basaltic and highlands of aluminum-rich anorthositic-type feldspar. An east-west asymmetry involving higher Al/Si ratios toward the east is noted; high concentrations of a KREEP-type component along the Imbrium-Procellarum edges and throughout the basin are also observed. Lunar K/Th ratios, lowest in areas of the Imbrium and higher in the surrounding mare and highlands, may lend support to the picture of the moon as a high-temperature condensate.

Adler, I.

Imaging of lunar surface chemistry from orbital X-ray data

Color images of the lunar surface from 20 deg W to 120 deg E were prepared which map the variations in the distribution of Al, Mg, and Si as expressed by the ratios of the Al/Si and the Mg/Al fluorescent X-ray intensities. Through the use of image enhancement techniques developed for the La Jolla Consortium on remote sensing of the moon, detailed information previously unobserved has been made available. The frequency distribution of the Apollo 15 and 16 intensity ratios for individual 0.25 x 0.25 deg surface units is clearly bimodal, peaking at 0.81 for mare material and 1.12 for nearside highland material, which values correspond to concentration ratios of 0.39 and 0.54, respectively, for Al/Si.

Bielefeld, M. J.

Chemical character of the partially flooded Smythii Basin based on Al/Si orbital X-ray data

Orbital X-ray fluorescence data indicate that continuous mare-basalt flooding is confined to the northeastern quadrant of the Smythii Basin. Al/Si values for soils in the unflooded northwestern section of the Smythii Basin closely approximate those for the adjacent terra to the west. Terra soils east of Mare Smythii, however, are unusually aluminous compared to terra soils west of the basin. This pronounced contrast between Al/Si values for terra soils to the east and west of Smythii as well as the minimal difference in values between the northwestern section of the basin and adjacent terra to the west are most likely due to a chemically homogeneous layer of ejecta from a large impact event west of Mare Smythii, such as that which formed the Crisium Basin. An alternate hypothesis is that the unflooded section of the basin is predominantly original basin floor material, indicating that the impact forming the 4km deep Smythii Basin did not penetrate into a horizon chemically different from the terra west of Smythii. The chemical contrast between the terra east and west of Smythii, then, would be ascribed to lateral heterogeneity within the lunar crust

Andre, C. G.

Palus Somni - Anomalies in the correlation of Al/Si X-ray fluorescence intensity ratios and broad-spectrum visible albedos

The positive correlation between Al/Si X-ray fluorescence intensity ratios determined during the Apollo 15 lunar mission and a broad-spectrum visible albedo of the moon is quantitatively established. Linear regression analysis performed on 246 1 degree geographic cells of X-ray fluorescence intensity and visible albedo data points produced a statistically significant correlation coefficient of .78. Three distinct distributions of data were identified as (1) within one standard deviation of the regression line, (2) greater than one standard deviation below the line, and (3) greater than one standard deviation above the line. The latter two distributions of data were found to occupy distinct geographic areas in the Palus Somni region.

Clark, P. E.